NCERT Solutions For Class 11 Chemistry Chapter 13 Hydrocarbons Very Short Questions And Answers
Question 1. Which hydrocarbon is obtained on hydrolysis of Al4C3?
Answer: CH4
Question 2. Name an alkane that cannot be prepared by the Wurtzreaction.
Answer: CH4
Question 3. Which alkane is expected to be formed when ethyl magnesium bromide is allowed to react with water?
Answer: Ethane
Question 4. How many acyclic isomers of C5H12 are possible?
Answer: Isomer
Question 5. What is the main constituent of CNG?
Answer: CH4
Question 6. Which type of aliphatic hydrocarbon undergoes substitution reaction?
Answer: Saturated
Question 7. What is the name of the alkene obtained when an aqueous solution of potassium succinate is electrolyzed?
Answer: Ethylene
Question 8. CH3CH=CH2HCl/peroxlde?
Answer: CH3CHClCH
Question 9. Which alkene on ozonolysis yields only acetaldehyde?
Answer: 2-butene
Question 10. What is Baeyer’s reagent? What is its use?
Answer: Alkaline KMnO4 ,it is used to identify C=C and C=C;
Question 11. What is Lindlar’s catalyst?
Answer: Pd-CaCO3/ (CH3COO)2Pb
Question 12. What is Teflon?
Answer: Polytetrafluoroethylene
Question 13. 2-butanone and ethanal are obtained when an alkene containing five carbon atoms is subjected to ozonolysis. State the position of the double bond in the alkene.
Answer: Doublebondis at C-2 of the alkene containing five carbon atoms
Question 14. What is mustard gas?
Answer: 2,2′- dichloro-diethyl sulfide;
Question 15. Name a reagent which can be used to distinguish between 2-butyne and 1-butyne.
Answer: Ammoniacal Cu2Cl2
Question 16. Which alkyne is used in Hawker’s Lamp?
Answer: HC=CH
Question 17. Mention the name of the compound obtained when acetylene reacts with arsenic chloride.
Answer: Lewisite
Question 18. What is the chemical name of Westron?
Answer: 1, 1,2,2- tetrachloroethane
Question 19. Mention one use ofWestrosol.
Answer: As an organic solvent
Question 20. What is obtained when acetylene is passed through a hot iron tube?
Answer: C6H6
Question 21. Give an example of an anti-knock compound.
Answer: Tetraethyl lead
Question 22. Which of the following cannot produce white precipitate by the action of ammoniacal AgNO3—Acetylene, dimethyl acetylene, methyl acetylene, ethyl acetylene. one acts as the base
Answer: Dimethyl acetylene
Question 23. Name the reagent which is used to carry out dihydroxylation of a double bond.
Answer: OsO4 followed by hydrolysis;
Question 24. Which polymer is used to make carry bags? Name its monomer.
Answer: 5. Polyethylene or Polythene, ethylene;
Question 25. Which compound is formed as the major product when propyne reacts with 20% H2SO4 in the presence of 1% HgSO4 at 80°C?
Answer: . Acetone (CH3COCH3)
Question 26. What is the state of hybridization of each carbon atom in an aromatic ring?
Answer: sp²
Question 27. Name the compound obtained by ozonolysis of benzene.
Answer: Glyoxal
Question 28. Give an example of a group that increases the rate of aromatic electrophilic substitution reaction.
Answer: —NH2
Question 29. Give an example of a group that decreases the rate of aromatic electrophilic substitution reaction.
Answer: —NO2
Question 30. Name an ortho-/para-orienting group.
Answer: Methyl (-CH3)
Question 31. Name a meta-orienting group.
Answer: Nitro ( —NO2)
Question 32. Give an example of a reversible electrophilic substitution reaction.
Answer: Sulphonationreaction
Question 33. Which is the smallest aromatic molecule/ion?
Answer: cyclopropenyl cation
Question 34. What is the orientation of the deactivating halogen atoms?
Answer: Ortho-/para
Question 35. Which heterocyclic compound remains as an impurity in benzene obtained from fractional distillation of coal tar?
Answer: Thiophene
Question 36. Which reagent is used in Birch reduction?
Answer: Na / liquid NH3, ethanol
Question 37. Which type of flame is observed during the combustion of benzene?
Answer: Sooty flame
Question 38. Nitration occurs at which position of the compound
Answer: Predominantly para position
Question 39. Which electrophile is involved in the desulphonation reaction
Answer: Proton (H+);
Question 40. Give an example of a carcinogen
Answer: 1, 2-benzpyrene
Question 41. Between HNO3 and H2SO4 which one acts as the base during the formation of N02 ion?
Answer: HNO3
Question 42. Which is the rate-determining step in an aromatic electrophilic substitution reaction?
Answer: First step, i.e., formation of σ -complex;
Question 43. Which step in aromatic electrophilic substitution reaction is exothermic?
Answer: Second step i.e., formation of substituted compound;
Question 44. Give an example of a neutral electrophile that participates in an electrophilic substitution reaction.
Answer: Sulphur trioxide;
Question 45. Give an example of a polynuclear hydrocarbon.
Answer: Anthracene
Question 46. Which compound other than anhydrous AlCl3 can be used for the ethylation of benzene?
Answer: FeCl3
Question 47. What is gamm exane? Mention its use.
Answer: BHC (Benzene hexachloride); as an insecticide
Question 48. What is the electrophile involved in the nitration reaction?
Answer: NO2
Question 49. Name the products obtained on pyrolysis of propane.
Answer: Propene, ethene, methane, and H2
Question 50. Which compound out of 1-butene, 1-butyne, and 2-butyne is most acidic?
Answer: 1-butyne is the most acidic.
Question 51. Write the name of the compound obtained when n-heptane is subjected to aromatization
Answer: Toluene (C6H5—CH3).
Question 52. Which alkane cannot be prepared by Kolbe’s method?
Answer: Methane (CH4).
Question 54. Write the names of the compounds obtained on ozonolysis of o-xylene.
Answer: Glyoxal, methyl glyoxal, and dimethyl glyoxal
Question 55. What is lindane?
Answer: Benzene hexachloride (BHC), C6H6Cl6.
Question 56. What is picric acid?
Answer: 2,4,6-trinitrophenol is known as picric acid
Question 57. What is the name of the compound obtained when benzene is oxidized by air (02) in the presence of a V205 catalyst heated at 500°C?
Answer: Maleic anhydride
Question 58. Which group out of -NO, and -CgHg is an o-/p directing group and which one is an o-/p-directing group?
Answer: NO2→m -directing; —C6H5→o-/p -directing
Question 59. Which will undergo nitration at a faster rate: C6H6 or C6H5Cl?
Answer: C6H6 undergoes nitration at a comparatively faster rate
Question 60. Name a group that is o -/p -directing but is also a deactivating group.
Answer: Chloro(-Cl)
Question 61. A hydrocarbon on ozonolysis produces ethanal and methanal.
Answer: CH3CH =CH2
Question 62. Mention the product:
Answer: CH3CHO
Question 63. Write the structure of an organic compound which reacts with water to yield methanal and hydrogen peroxide
Answer:
Question 64. Benzene reacts with CH3COCl in the presence of anhydrous AlCl3 to form (an organic compound).
Answer: Acetophenone.
Question 65. Which reagent can be used for the following conversion? HC≡CH→HC=CH2
Answer: H2,Pd-CaCO3/Pb(OAc)2 (Lindler’s catalyst)
NCERT Solutions For Class 11 Chemistry Chapter 13 Hydrocarbons Fill In The Blanks
Question 1. The formula of marsh gas is _______________
Answer: CH4
Question 2. _______________ are called paraffins.
Answer: Alkanes
Question 3. Beryllium carbide yields _______________
Answer: CH4
Question 4. Dutch oil is _______________
Answer: 1,2-dichloroethane;
Question 5. Wurtz reaction is suitable for the preparation of _______________alkanes.
Answer: Symmetrical
Question 6. CHgCOCHg undergoes Clemmensen reduction to yield _______________
Answer: Propane
Question 7.___________ can be identified by Schryver’s colour test
Answer: CH
Question 8. Peroxide effect is applicable only for _______________
Answer: HBr
Question 9. _______________ is obtained when. a solution of sodium butanoate is electrolyzed
Answer: n-hexane
Question 10. Isobutylmagnesium bromide reacts with water to form _______________
Answer: Isobutane
Question 11. _______________ on ozonolysis produces formaldehyde and acetaldehyde.
Answer: Propene
Question 12. _______________ is obtained as the major product when 2- butanol is dehydrated.
Answer: But 2 ene
Question Benzene is a polymer of _______________
Answer: Acetylene
Question 14. The simplest hydrocarbon which reacts with ammoniacal silver nitrate to produce a white precipitate is _________
Answer: Acetylene
Question 15. _______________ is obtained when 2-butyne is passed through a mixture of 20% H2SO4 and 1% H2SO4
Answer: 2 – butanone
Question 16. Hexamethylbenzene is the trimer of _______________
Answer: 2 butyne
Question 17. When a mixture of _________ and Ag – powder is heated ________________ is obtained as the product
Answer: Chloroform, acetylene
Question 18. The values of boiling and melting points of alkadienes are _ than the corresponding alkanes and alkenes containing a same number of carbon atoms.
Answer: Higher
Question 19. Ozonolysis of acetylene forms _______________
Answer: Glyoxal
Question 20. Two molecules of HBr react with acetylene to form _______________
Answer: 1,1 dibromomoethane
Question 21. If an alkene forms only one type of carbonyl compound on ozonolysis, then it can be concluded that the alkene is _______________
Answer: Symmetrical
Question 22. CxHy _______________ xCO2 + + y/2 H2O Heat
Answer: \(\left(x+\frac{y}{4}\right) \mathrm{O}_2\)
Question 23. The number of isomeric tribromobenze is _______________
Answer: Three
Question 24. 1,3,5-trinitrobenzene is an_ compound. _______________
Answer: Explosive
Question 25. The resonance-stabilised carbocation formed in the first step of the electrophilic substitution reaction is called _______________
Answer: Sigma complex
Question 26. _______________ of benzene is carried out by using N+O4 BF–4 salt.
Answer: Nitration
Question 27. When benzene is oxidized by atmospheric oxygen in the presence of V2O5 at high temperature, _______________ is obtained.
Answer: Maleic anhydride
Question 28. The product obtained due to Birch reduction of benzene when subjected to ozonolysis forms only _______________
Answer: Propanediol
Question 29. —COOH is a/an ______________ Group but COO is an __________ group
Answer: Deactivating, activating;
Question 30. NH2 group _______________ electron density at ortho-/para positions of the rin
Answer: Increases;
Question 31. —NO2 group ______________ electron density at the meta position of the ring
Answer: Decreases
Question 32. C —C bond lengths of benzene are _________________
Answer: Equivalent
Question 33. Fill in the blank __________(organic compound) is obtained when an aqueous solution of potassium succinate is electrolyzed.
Answer: Ethylene